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Partial pressure of carbon dioxide, temperature, salinity and other variables collected from surface underway observations during Ships of Opportunity (SOOP) C/S Allure of the Seas lines in the Caribbean Sea, Gulf of Mexico and North Atlantic Ocean in 2019 (NCEI Accession 0184598)

INVESTIGATORS:
Rik Wanninkhof ORCID logo - NOAA Atlantic Oceanographic and Meteorological Laboratory (AOML)
Denis Pierrot ORCID logo - NOAA Atlantic Oceanographic and Meteorological Laboratory (AOML)
Kevin F. Sullivan - NOAA Atlantic Oceanographic and Meteorological Laboratory (AOML)

PACKAGE DESCRIPTION: This dataset consists of sea surface underway measurements of partial pressure of carbon dioxide, temperature, salinity and barometric pressure during the Ship of Opportunity (SOOP) C/S Allure of the Seas cruise lines in the Caribbean Sea, Gulf of Mexico and North Atlantic Ocean in from 2019-01-13 to 2020-01-05. In 2015, the Ocean Carbon Group at NOAA's Atlantic Oceanographic and Meteorological Laboratory (AOML) installed an autonomous instrument to measure CO2 levels in surface water and air on the Cruise Ship (C/S) Allure of the Seas.

CITE AS: Wanninkhof, Rik; Sullivan, Kevin F.; Pierrot, Denis (2019). Partial pressure of carbon dioxide, temperature, salinity and other variables collected from surface underway observations during Ships of Opportunity (SOOP) C/S Allure of the Seas lines in the Caribbean Sea, Gulf of Mexico and North Atlantic Ocean in 2019 (NCEI Accession 0184598). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.25921/3yhw-bf95. Accessed [date].


IDENTIFICATION INFORMATION FOR THIS DATA PACKAGE:
NCEI ACCESSION: 0184598
NCEI DOI: https://doi.org/10.25921/3yhw-bf95
EXPOCODE: BHAF20190113; BHAF20190120; BHAF20190127; BHAF20190203; BHAF20190210; BHAF20190217; BHAF20190224; BHAF20190303; BHAF20190421; BHAF20190428; BHAF20190505; BHAF20190512; BHAF20190519; BHAF20190526; BHAF20190602; BHAF20190609; BHAF20190616; BHAF20190623; BHAF20190630; BHAF20190707; BHAF20190714; BHAF20190721; BHAF20190728; BHAF20190804; BHAF20190811; BHAF20190818; BHAF20190825; BHAF20190904; BHAF20190908; BHAF20190915; BHAF20190922; BHAF20190929; BHAF20191006; BHAF20191013; BHAF20191020; BHAF20191027; BHAF20191103; BHAF20191110; BHAF20191117; BHAF20191124; BHAF20191201; BHAF20191208; BHAF20191215; BHAF20191222; BHAF20191229;
CRUISE ID: ALoS_20190113; ALoS_20190120; ALoS_20190127; ALoS_20190203; ALoS_20190210; ALoS_20190217; ALoS_20190224; ALoS_20190303; ALoS_20190421; ALoS_20190428; ALoS_20190505; ALoS_20190512; ALoS_20190519; ALoS_20190526; ALoS_20190602; ALoS_20190609; ALoS_20190616; ALoS_20190623; ALoS_20190630; ALoS_20190707; ALoS_20190714; ALoS_20190721; ALoS_20190728; ALoS_20190804; ALoS_20190811; ALoS_20190818; ALoS_20190825; ALoS_20190904; ALoS_20190908; ALoS_20190915; ALoS_20190922; ALoS_20190929; ALoS_20191006; ALoS_20191013; ALoS_20191020; ALoS_20191027; ALoS_20191103; ALoS_20191110; ALoS_20191117; ALoS_20191124; ALoS_20191201; ALoS_20191208; ALoS_20191215; ALoS_20191222; ALoS_20191229;
SECTION/LEG: SOOP;

TYPES OF STUDY:
Surface underway;

TEMPORAL COVERAGE:
START DATE: 2019-01-13
END DATE: 2020-01-05

SPATIAL COVERAGE:
NORTH: 26.43
WEST: -87.69
EAST: -62.98
SOUTH: 16.22

GEOGRAPHIC NAMES:
Atlantic Ocean;Caribbean Sea;Gulf of Mexico;

PLATFORMS:
Cruise Ship Allure of the Seas (ID: BHAF);

RESEARCH PROJECT(S):
Ship Of Opportunity Program (SOOP);


VARIABLES / PARAMETERS:

pCO2 (fCO2) autonomous
Abbreviation: fCO2_SW@SST
Unit: uatm
Observation type: Surface underway
Measured or calculated: Measured
Sampling instrument: Seawater pump
Location of seawater intake: Bow
Analyzing instrument: Infrared Analyzer: LI-COR model 6262
Detailed sampling and analyzing information: Pierrot, D., Neill, C., Sullivan, K., Castle, R., Wanninkhof, R., Lüger, H., Johannessen, T., Olsen, A., Feely, R. A., & Cosca, C. E. (2009). Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines. Deep Sea Research Part II: Topical Studies in Oceanography, 56(8-10), 512-522. https://doi.org/10.1016/j.dsr2.2008.12.005
Equilibrator type: Spray head above dynamic pool, with thermal jacket
Equilibrator volume: 0.95 L (0.4 L water, 0.55 L headspace)
Is the equilibrator vented or not: Vented
Water flow rate: 1.5 - 2.0 L/min
Gas flow rate: 70 - 150 ml/min
How was temperature inside the equilibrator measured: Hart Scientific model 1523 digital thermometer
How was pressure inside the equilibrator measured: External Setra 270 connected to the exit of the analyzer
Drying method for gas: Gas stream passes through a thermoelectric condenser (~5 C) and then through a Perma Pure (Nafion) dryer before reaching the analyzer (90% dry).
SEA CO2 gas detector manufacturer: Licor, Inc
SEA CO2 gas detector model: Licor 6262
SEA CO2 gas detector resolution: Accuracy: +/- 2 uatm in fCO2_SW
SEA CO2 gas detector uncertainty: Precision: +/- 0.01 uatm in fCO2_SW
Standardization technique: The system runs a full cycle in approximately 5 hours. The cycle starts with 4 standard gases, then measures three rounds of 6 atmopherice samples followed by 50 surface water samples. Each new gas is flushed through the Licor Analyzer for 2 minutes prior to a stop-flow measurement.
Standardization frequency: Every 7 hours
Standard gas manufacturer: Standard gases are supplied by NOAA Earth System Research Laboratory, Global Monitoring Division, in Boulder, CO, and are directly traceable to the WMO scale.
Standard gas concentration: Std 1: CA04890, 282.59 ppm, owned by ESRL, used every ~4.5 hours. Std 2: CC115007, 381.53 ppm, owned by ESRL, used every ~4.5 hours. Std 3: CA06380, 448.34 ppm, owned by ESRL, used every ~4.5 hours. Std 4: CB09022, 537.41 ppm, owned by ESRL, used every ~4.5 hours. Std 5: LL100000, 0.00 ppm, owned by AOML, used every ~27.0 hours.
Standard gas uncertainty: 0.01 ppm
Water vapor correction method: Details of the data reduction are described in Pierrot, et.al. (2009).
Temperature correction method: Details of the data reduction are described in Pierrot, et.al. (2009).
At what temperature was pCO2 reported: In situ sea surface temperature
Uncertainty: 0.01C
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value
Method reference: Pierrot, D., Neill, C., Sullivan, K., Castle, R., Wanninkhof, R., Lüger, H., Johannessen, T., Olsen, A., Feely, R. A., & Cosca, C. E. (2009). Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines. Deep Sea Research Part II: Topical Studies in Oceanography, 56(8-10), 512-522. https://doi.org/10.1016/j.dsr2.2008.12.005
Researcher name: Denis Pierrot
Researcher institution: NOAA/AOML
Sea Surface Temperature
Abbreviation: SST_C
Unit: degrees celcius
Observation type: Surface Underway
Analyzing instrument: SBE 38, Seabird, Inc.
Detailed sampling and analyzing information: In Bow Thruster room, about 1m after the intake which is directly through the ship's hull, before the SW pump
Uncertainty: Accuracy: 0.001C, Precision: 0.0003C
Researcher name: Maintained by University of Miami MTG group
Researcher institution: University of Miami
Sea Surface Salinity
Abbreviation: SAL_permil
Observation type: Surface Underway
Analyzing instrument: SBE 45, Seabird, Inc.
Uncertainty: Accuracy: +/- 0.005; Precision: 0.0002
Researcher name: Maintained by University of Miami MTG group
Researcher institution: University of Miami
Atmospheric Pressure
Abbreviation: PRES_ATM@SSP_hPa
Unit: hPa
Sampling instrument: Vaisala, WXT520
Uncertainty: Accuracy: +/- 0.5 hPa; Precision: 0.1 hPa
Researcher name: Maintained by University of Miami MTG group
Researcher institution: University of Miami

PUBLICATIONS DESCRIBING THIS DATASET:
Pierrot, D., Neill, C., Sullivan, K., Castle, R., Wanninkhof, R., Lüger, H., Johannessen, T., Olsen, A., Feely, R. A., & Cosca, C. E. (2009). Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines. Deep Sea Research Part II: Topical Studies in Oceanography, 56(8-10), 512-522. https://doi.org/10.1016/j.dsr2.2008.12.005
Feely, R.A., R. Wanninkhof, H.B. Milburn, C.E. Cosca, M. Stapp, and P.P. Murphy, A new automated underway system for making high precision pCO2 measurements onboard research ships, Analytica Chim. Acta, 377, 185-191, 1998.
Wanninkhof, R., & Thoning, K. (1993). Measurement of fugacity of CO2 in surface water using continuous and discrete sampling methods. Marine Chemistry, 44(2–4), 189–204. https://doi.org/10.1016/0304-4203(93)90202-y
ADDITIONAL INFORMATION:
none;
FUNDING AGENCY:
NOAA Climate Program Office Program
PROJECT TITLE: Surface Water pCO2 Measurements from Ships of Opportunity (SOOP)
PROJECT ID:

SUBMITTED BY: Kevin F. Sullivan (Kevin.Sullivan@noaa.gov)

SUBMISSION DATE: 2019-01-30

REVISION DATE: 2020-01-17

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