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Carbon Dioxide, Hydrographic, and Chemical Data Obtained During NOAA Ship Ronald H. Brown Cruise in the South Atlantic Ocean on GO-SHIP/CLIVAR Repeat Hydrography Section A16S from 2013-12-23 to 2014-02-04 (NCEI Accession 0167410)

INVESTIGATORS:
Rik Wanninkhof ORCID logo - NOAA Atlantic Oceanographic and Meteorological Laboratory (AOML)
Leticia Barbero ORCID logo - NOAA Atlantic Oceanographic and Meteorological Laboratory (AOML)
Frank J. Millero - Rosenstiel School of Marine and Atmospheric Science (RSMAS)
Dennis A. Hansell ORCID logo - Rosenstiel School of Marine and Atmospheric Science (RSMAS)

PACKAGE DESCRIPTION: This dataset includes discrete bottle measurements of dissolved inorganic carbon (DIC), total alkalinity, pH on sea water scale, partial pressure of CO2, dissolved organic carbon (DOC, TDN), CFCs (CFC-11, CFC-12), delta C14, delta C13, temperature, salinity, dissolved oxygen, nutrients, and other variables measured during NOAA Ship Ronald H. Brown GO-SHIP Section A16S_2013 cruise RB1307 (EXPOCODE 33RO20131223) in the South Atlantic Ocean, from 2013-12-23 to 2014-02-04.

CITE AS: Wanninkhof, Rik; Barbero, Leticia; Baringer, Molly O.; Bullister, John L.; Feely, Richard A.; Millero, Frank J.; Hansell, Dennis A.; Zhang, Jia-Zhong; Mordy, Calvin; Langdon, Chris; Schlosser, Peter; Jenkins, William J.; McNichol, Ann; Key, Robert M. (2017). Carbon Dioxide, Hydrographic, and Chemical Data Obtained During NOAA Ship Ronald H. Brown Cruise in the South Atlantic Ocean on GO-SHIP/CLIVAR Repeat Hydrography Section A16S from 2013-12-23 to 2014-02-04 (NCEI Accession 0167410). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.7289/v5vq30xb. Accessed [date].


IDENTIFICATION INFORMATION FOR THIS DATA PACKAGE:
NCEI ACCESSION: 0167410
NCEI DOI: https://doi.org/10.7289/v5vq30xb
EXPOCODE: 33RO20131223;
CRUISE ID: RB1307;
SECTION/LEG: GO-SHIP A16S;

TYPES OF STUDY:
Discrete measurement;

TEMPORAL COVERAGE:
START DATE: 2013-12-23
END DATE: 2014-02-04

SPATIAL COVERAGE:
NORTH: -6
WEST: -36.4
EAST: -24.9
SOUTH: -60.1

GEOGRAPHIC NAMES:
South Atlantic Ocean;

PLATFORMS:
R/V Ronald H. Brown (ID: 33RO);

RESEARCH PROJECT(S):
none;


VARIABLES / PARAMETERS:

Dissolved Inorganic Carbon
Abbreviation: TCARBN
Unit: UMOL/KG
Observation type: Discrete, bottle
Measured or calculated: Measured
Sampling instrument: CDT Bottles
Analyzing instrument: Coulometric measurement system (SOMMA)
Standardization description: Injection of 2 pairs of sample loops of known volume of pure CO2 bracketing the expected values of TCO2 and analysis of Certified Reference Materials supplied by Dr. A Dickson of SIO. TCO2 values were corrected for the addition of mercuric chloride and for the offset from the CRM value.
CRM manufacturer: Andrew Dickson Laboratory at SIO
CRM batch number: 129
Preservation method: mercuric chloride solution
Preservative volume: 100 mL
Preservative correction: AOML3: -3.22 uMol/kg, AOML4: 1.57 uMol/kg (Avg corrections)
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value
Method reference: Johnson, K., Wills, K., Butler, D., Johnson, W., and Wong, C.: Coulometric total carbon dioxide analysis for marine studies: maximizing the performance of an automated gas extraction system and coulometric detector, Mar. Chem., 44, 167-187, https://doi.org/10.1016/0304-4203(93)90201-X, 1993. 2193.
Researcher name: Robert Castle
Researcher institution: AOML
Total alkalinity
Abbreviation: ALKALI
Unit: UMOL/KG
Observation type: Discrete, bottle
Measured or calculated: Measured
Sampling instrument: CTD Bottles
Type of titration: HCl titration in close cell
Cell type (open or closed): closed
Curve fitting method: Levenberg-Marquardt nonlinear least-squares fit of full titration
Detailed sampling and analyzing information: Millero, F.J., J.-Z. Zhang, K, Lee, and D.M. Campbell, 1993: Titration alkalinity of seawater. Mar. Chem., 44, 153-165.
Uncertainty: Accuracy based on CRM batch 129 for system A +/- 1.85 umol/kg and for system B +/- 3.00 umol/kg. Precision based on duplicate measurements for system A +/- 1.84 umol/kg and for system B +/- 1.69 umol/kg between the systems +/- 2.74 umol/kg
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value
Method reference: Millero, F.J., J.-Z. Zhang, K, Lee, and D.M. Campbell, 1993: Titration alkalinity of seawater. Mar. Chem., 44, 153-165.
Researcher name: Ryan Woosley
Researcher institution: RSMAS, University of Miami
pCO2
Abbreviation: Discrete Partial Pressure of CO2
Unit: UMOL/KG
Observation type: Bottle, discrete
Sampling instrument: CTD
Analyzing instrument: Licor model 840
Detailed sampling and analyzing information: Circulation of dried headspace sample gas through a non-dispersive infrared analyzer (Licor model 840). The system is a prototype built by Tim Newberger (NOAA/ESRL/CIRES) and supported by C. Sweeney and T. Takahashi. For further details see the cruise report.
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value
Method reference: Chipman, D.W., J. Marra, and T. Takahashi, 1993: Primary production at 47°N and 20°W in the North Atlantic Ocean: A comparison between the 14C incubation method and mixed layer carbon budget observations. Deep-Sea Res., II, v. 40, pp. 151-169.
Researcher name: Rik Wanninkhof
Researcher institution: AOML
DOC
Abbreviation: Dissolved Organic Carbon
Unit: UMOL/KG
Observation type: Bottle, discrete
Sampling instrument: CTD
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value
Researcher name: Dennis Hansell
Researcher institution: RSMAS
CTD Temperature
Abbreviation: CTDTMP
Unit: degrees celcius
Observation type: CTD sensor
Sampling instrument: CTD
Analyzing instrument: CTD
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value
Researcher name: Kristene McTaggart
Researcher institution: PMEL
CTD Salinity
Abbreviation: CTDSAL
Observation type: CTD sensor
Sampling instrument: CTD
Analyzing instrument: CTD
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value
Researcher name: Kristene McTaggart
Researcher institution: PMEL
Bottle Salinity
Abbreviation: SALNTY
Observation type: Bottle, discrete
Sampling instrument: CTD
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value
Researcher name: Edward Hunt
Researcher institution: Contract
CTD Oxygen
Abbreviation: CTDOXY
Unit: UMOL/KG
Observation type: CTD sensor
Sampling instrument: CTD
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value
Researcher name: Kristene McTaggart
Researcher institution: PMEL
Bottle Oxygen
Abbreviation: OXYGEN
Unit: UMOL/KG
Observation type: Bottle, discrete
Sampling instrument: CTD
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value
Researcher name: Laura Stoltenberg
Researcher institution: RSMAS
Nutrients
Abbreviation: SILCAT, NITRAT, NITRIT PHSPHT
Unit: UMOL/KG
Observation type: Bottle, discrete
Sampling instrument: CTD
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value
Researcher name: CharlesFischer
Researcher institution: AOML
Chlorofluorocarbon
Abbreviation: CFCs/SF6
Unit: PMOL/KG
Observation type: Bottle, discrete
Sampling instrument: CTD
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value
Researcher name: David Wisegarver
Researcher institution: PMEL

PUBLICATIONS DESCRIBING THIS DATASET:
Johnson, K. M., A. Körtzinger, L. Mintrop, J. C. Duinker, and D. W. R. Wallace. 1999. “Coulometric total carbon dioxide analysis for marine studies: Measurement and internal consistency of underway surface TCO2 concentrations.” Marine Chemistry 67:123-44.
Wanninkhof, R., & Thoning, K. (1993). Measurement of fugacity of CO2 in surface water using continuous and discrete sampling methods. Marine Chemistry, 44(2–4), 189–204. https://doi.org/10.1016/0304-4203(93)90202-y
Pierrot, D., Neill, C., Sullivan, K., Castle, R., Wanninkhof, R., Lüger, H., Johannessen, T., Olsen, A., Feely, R. A., & Cosca, C. E. (2009). Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines. Deep Sea Research Part II: Topical Studies in Oceanography, 56(8-10), 512-522. https://doi.org/10.1016/j.dsr2.2008.12.005
ADDITIONAL INFORMATION:
none;
FUNDING AGENCY:
NSF, NOAA
PROJECT TITLE: Repeat Hydrography Sections observations
PROJECT ID:

SUBMITTED BY: Rik Wanninkhof (Rik.Wanninkhof@noaa.gov)

SUBMISSION DATE: 2017-10-18

REVISION DATE: 2021-08-31

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