Partial pressure of carbon dioxide, dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from the surface underway observations and discrete bottle samples from CCGS Amundsen during the cruises in Baffin Bay, Nares Strait, and Lancaster Sound from 2013-08-11 to 2014-08-12 (NCEI Accession 0167322)
PACKAGE DESCRIPTION: This dataset includes surface underway and discrete bottle chemical, physical and meteorological data collected from CCGS Amundsen during the cruises in Baffin Bay, Nares Strait, and Lancaster Sound from 2013-08-11 to 2014-08-12. These data include underway measurements of partial pressure of carbon dioxide (pCO2) in the equilibrator headspace (dry) at equilibrator temperature, barometric pressure, sea surface temperature, sea surface salinity, discrete measurements of dissolved inorganic carbon, total alkalinity and stable oxygen isotope data. These data were collected by Tim Papakyriakou, Tonya Burgers and Sebastian Luque of University of Manitoba, Canada, Brent Else of University of Calgary, Canada, Helmuth Thomas of Dalhousie University, Canada, and Alfonso Mucci of McGill University, Canada as part of the CCGS Amundsen Canadian Arctic, ArcticNet cruises during the 2013-2014.
CITE AS: Papakyriakou, Tim; Miller, Lisa A.; Thomas, Helmuth; Mucci, Alfonso; Else, Brent (2017). Partial pressure of carbon dioxide, dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from the surface underway observations and discrete bottle samples from CCGS Amundsen during the cruises in Baffin Bay, Nares Strait, and Lancaster Sound from 2013-08-11 to 2014-08-12 (NCEI Accession 0167322). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.7289/v5st7n3c. Accessed [date].
none;
Discrete measurement;Surface underway;
TEMPORAL COVERAGE:
SPATIAL COVERAGE:
GEOGRAPHIC NAMES:
PLATFORMS:
RESEARCH PROJECT(S):
VARIABLES / PARAMETERS:
Dissolved Inorganic Carbon | |
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Abbreviation: | TCARBN |
Unit: | UMOL/KG |
Observation type: | Discrete, bottle |
Measured or calculated: | Measured |
Sampling instrument: | niskin bottle on 24-bottle rosette |
Analyzing instrument: | VINDTA 3C |
Detailed sampling and analyzing information: | DIC was determined by coulometric titration |
Replicate information: | 10% of all sampes were collected in duplicate from the same niskin bottle |
CRM manufacturer: | Andrew Dickson's lab at Scripps Institution of Oceanopgraphy |
Preservation method: | saturated solution of mercury (II) chloride |
Preservative volume: | 100 uL of mercuric chloride was added to 500 mL samples |
Uncertainty: | reproducibility better than 1 umol/kg |
Quality flag convention: | WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value |
Researcher name: | Jacoba Mol |
Researcher institution: | Dalhousie University |
Total alkalinity | |
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Abbreviation: | ALKALI |
Unit: | UMOL/KG |
Observation type: | Discrete, bottle |
Measured or calculated: | Measured |
Sampling instrument: | niskin bottle on 24-bottle rosette |
Analyzing instrument: | VINDTA 3C |
Type of titration: | potentiometric titration |
Replicate information: | 10% of all sampes were collected in duplicate from the same niskin bottle |
CRM manufacturer: | Andrew Dickson's lab at Scripps Institution of Oceanopgraphy |
Preservation method: | saturated solution of mercury (II) chloride |
Preservative volume: | 100 uL of mercuric chloride was added to 500 mL samples |
Uncertainty: | reproducibility better than 2 umol/kg |
Quality flag convention: | WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value |
Researcher name: | Jacoba Mol |
Researcher institution: | Dalhousie University |
pCO2 (fCO2) autonomous | |
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Abbreviation: | pCO2_SW |
Unit: | micro-atmosphere |
Observation type: | Surface underway |
Measured or calculated: | calculated |
Calculation method and parameters: | pCO2 is calculated from the CO2 molar fraction, the equilibrator pressure, and the water vapour pressure (estimated from surface water salinity and temperature using Weiss and Price [1980]) following Dickson et al. [2007] |
Sampling instrument: | GO 8050 underway pCO2 system |
Analyzing instrument: | Licor 7000 |
Detailed sampling and analyzing information: | See Pierrot et al. [2009] for more details on GO 8050 underway system |
Equilibrator type: | shower-type equilibrator |
Is the equilibrator vented or not: | Vented |
Water flow rate: | 2.0 L/min |
How was temperature inside the equilibrator measured: | See Pierrot et al. [2009] |
How was pressure inside the equilibrator measured: | See Pierrot et al. [2009] |
Drying method for gas: | See Pierrot et al. [2009] |
SEA CO2 gas detector manufacturer: | Licor, Inc |
SEA CO2 gas detector model: | Licor 7000 |
SEA CO2 gas detector resolution: | 0.02 ppm |
SEA CO2 gas detector uncertainty: | 0.01 ppm |
Standardization technique: | twice daily |
Standard gas concentration: | 0 ppm, 377.90 ppm, and 600.02 ppm |
Uncertainty: | 4% |
Researcher name: | Tim Papakyriakou |
Researcher institution: | University of Manitoba |
CO2 molar fraction | |
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Abbreviation: | xCO2_EQU |
Unit: | micromol per mol (or ppm) |
Observation type: | surface underway |
Sampling instrument: | GO 8050 underway pCO2 system |
Analyzing instrument: | LI-7000 gas analyzer |
Uncertainty: | accuracy of nominal +/- 1% |
Researcher name: | Tonya Burgers |
Researcher institution: | University of Manitoba |
H2O molar fraction | |
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Abbreviation: | xH2O_EQU |
Unit: | millimol per mol (or ppt) |
Observation type: | surface underway |
Sampling instrument: | GO 8050 underway pCO2 system |
Analyzing instrument: | LI-7000 |
Uncertainty: | accuracy of nominal +/- 1% |
Researcher name: | Tonya Burgers |
Researcher institution: | University of Manitoba |
temperature of gas analyzer | |
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Abbreviation: | TEMP_LICOR |
Unit: | degrees celcius |
Observation type: | surface underway |
Sampling instrument: | GO 8050 underway pCO2 system |
Analyzing instrument: | LI-7000 |
Uncertainty: | accuracy of nominal +/- 1% |
Researcher name: | Tonya Burgers |
Researcher institution: | University of Manitoba |
pressure of gas analyzer | |
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Abbreviation: | PRES_LICOR |
Unit: | hPa |
Observation type: | surface underway |
Sampling instrument: | GO 8050 underway pCO2 system |
Analyzing instrument: | LI-7000 |
Uncertainty: | accuracy of nominal +/- 1% |
Researcher name: | Tonya Burgers |
Researcher institution: | University of Manitoba |
pressure of equilibrator | |
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Abbreviation: | PRES_EQU |
Unit: | hPa |
Observation type: | surface underway |
Sampling instrument: | GO 8050 underway pCO2 system |
Analyzing instrument: | GO 8050 underway pCO2 system |
Uncertainty: | accuracy of nominal +/- 1% |
Researcher name: | Tonya Burgers |
Researcher institution: | University of Manitoba |
temperature of water inside equilibrator | |
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Abbreviation: | TEMP_EQU |
Unit: | degrees celcius |
Observation type: | surface underway |
Sampling instrument: | GO 8050 underway pCO2 system |
Analyzing instrument: | Hart thermometer |
Uncertainty: | accuracy of 0.5 deg C |
Researcher name: | Tonya Burgers |
Researcher institution: | University of Manitoba |
sea surface temperature | |
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Abbreviation: | SST |
Unit: | degrees celcius |
Observation type: | surface underway |
Analyzing instrument: | type T thermocouple |
Uncertainty: | accuracy of 0.5 deg C |
Researcher name: | Tonya Burgers |
Researcher institution: | University of Manitoba |
sea surface salinity | |
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Abbreviation: | SSS |
Observation type: | surface underway |
Sampling instrument: | GO 8050 underway pCO2 system |
Analyzing instrument: | Idronaut Ocean Seven model 315 |
Uncertainty: | accuracy of 0.003 mS/cm in conductivity measurement |
Researcher name: | Tonya Burgers |
Researcher institution: | University of Manitoba |
seawater temperature | |
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Abbreviation: | CTDTMP |
Unit: | degrees celcius |
Observation type: | discrete bottle |
Sampling instrument: | CTD |
Analyzing instrument: | Sea Bird 911plus+ |
Uncertainty: | accuracy of 0.001 deg C |
Researcher name: | Jacoba Mol |
Researcher institution: | Dalhousie University |
seawater salinity | |
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Abbreviation: | CTDSAL |
Observation type: | discrete bottle |
Sampling instrument: | CTD |
Analyzing instrument: | Sea Bird 911plus+ |
Detailed sampling and analyzing information: | salinity measurements from the Sea Bird 911plus+ were calibrated using bottles samples for salinity run on an Autosal model 8400B |
Uncertainty: | accuracy of 0.0003 S/m for conductivity measurements |
Method reference: | equation of state EOS 80 |
Researcher name: | Jacoba Mol |
Researcher institution: | Dalhousie University |
delta-O-18 | |
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Abbreviation: | DELO18 |
Unit: | per mille |
Observation type: | discrete bottle |
Sampling instrument: | niskin bottle on 24-bottle rosette |
Analyzing instrument: | Micromass Isoprime universal triple collector mass spectrometer |
Detailed sampling and analyzing information: | Samples were analyzed using the CO2 equilibration method. The CO2 was then analyzed on a mass spectromoter in dual inlet mode with an AquaPrep system. For each analytical sequence two internal reference water samples were used to normalize the sample data. |
Uncertainty: | 0.05 per mille in replicate measurements |
Researcher name: | Jacoba Mol |
Researcher institution: | Dalhousie University |
SUBMITTED BY: Tonya M. Burgers (tonya.burgers@umanitoba.ca)
SUBMISSION DATE: 2017-10-11
REVISION DATE: 2018-06-22
PREVIOUS VERSIONS: Version 1.1Version 2.2