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Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the METEOR in the North Atlantic Ocean and South Atlantic Ocean from 2002-10-13 to 2002-11-16 (NCEI Accession 0113890)

INVESTIGATOR:
Douglas W. R. Wallace - Dalhousie University; Institute of Oceanography

PACKAGE DESCRIPTION: This dataset includes chemical, discrete sample, physical and profile data collected from METEOR in the North Atlantic Ocean and South Atlantic Ocean from 2002-10-13 to 2002-11-16 and retrieved during cruise CARINA/06MT20021013. These data include ALKALINITY, AMMONIUM, DISSOLVED INORGANIC CARBON, DISSOLVED OXYGEN, HYDROSTATIC PRESSURE, NITRATE, NITRITE, PHOSPHATE, Potential temperature (theta), SALINITY, SILICATE and WATER TEMPERATURE. The instruments used to collect these data include CTD and bottle. These data were collected by Douglas Wallace of Universitat Kiel; Institut Fur Meereskunde; Forschungsbereich Marine Biogeochemie as part of the CARINA/06MT20021013 data set. The CARINA (CARbon dioxide IN the Atlantic Ocean) data synthesis project is an international collaborative effort of the EU IP CARBOOCEAN, and U.S. partners. It has produced a merged internally consistent dataset of open ocean subsurface measurements for biogeochemical investigations, in particular, studies involving the carbon system. The original focus area was the North Atlantic Ocean, but over time the geographic extent expanded and CARINA now includes data from the entire Atlantic, the Arctic Ocean, and the Southern Ocean.

CITE AS: Wallace, Douglas W. R. (2013). Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the METEOR in the North Atlantic Ocean and South Atlantic Ocean from 2002-10-13 to 2002-11-16 (NCEI Accession 0113890). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.3334/cdiac/otg.carina_06mt20021013. Accessed [date].


DATA PACKAGES RELATED TO THIS ONE:
none;
IDENTIFICATION INFORMATION FOR THIS DATA PACKAGE:
NCEI ACCESSION: 0113890
NCEI DOI: https://doi.org/10.3334/cdiac/otg.carina_06mt20021013
EXPOCODE: 06MT20021013; 06MT55;
CRUISE ID: CARINA/06MT20021013;
SECTION/LEG: CARINA/06MT20021013;

TYPES OF STUDY:
Discrete measurement;Profile;

TEMPORAL COVERAGE:
START DATE: 2002-10-13
END DATE: 2002-11-16

SPATIAL COVERAGE:
NORTH: 11.967
WEST: -56.641
EAST: -13.999
SOUTH: 0

GEOGRAPHIC NAMES:
Atlantic Ocean;

PLATFORMS:
Meteor (ID: 06MT);

RESEARCH PROJECT(S):
none;


VARIABLES / PARAMETERS:

Dissolved Inorganic Carbon
Abbreviation: DIC
Observation type: discrete
In-situ / Manipulation / Response variable: In-situ observation
Measured or calculated: Calculated
Detailed sampling and analyzing information: Coulometric titration [Johnson et al., 1993]. CRM corrected from batch 60. Mean offset between our measurements and the Certified Values was 0.12 +/- 0.84 μmol kg-1 (95% confidence interval, n = 17). Measured DIC concentrations were therefore adjusted to the Certified calibration scale by subtraction of this mean offset. The DIC samples were measured after the cruise in the lab in Kiel.
Total alkalinity
Abbreviation: TA
Observation type: discrete
In-situ / Manipulation / Response variable: In-situ observation
Measured or calculated: Measured
Curve fitting method: Potentiometric titration [Mintrop et al., 2000]. CRM corrected from batch 60. The mean difference between measurements and the Certified values was 0.8 +/- 2.37 μmol kg-1 (95% confidence interval, n=16). Alkalinity values have been adjusted to the certified value by addition of this mean offset. The alkalinity samples were measured after the cruise in the lab in Kiel.
CTDTMP
Abbreviation: CTDTMP
Unit: DEG_C
Controlled vocabulary name: WATER TEMPERATURE
In-situ / Manipulation / Response variable: in-situ
CTDSAL
Abbreviation: CTDSAL
Controlled vocabulary name: SALINITY
In-situ / Manipulation / Response variable: in-situ
OXYGEN
Abbreviation: OXYGEN
Unit: UMOL/KG
Controlled vocabulary name: DISSOLVED OXYGEN
In-situ / Manipulation / Response variable: in-situ
SILCAT
Abbreviation: SILCAT
Unit: UMOL/KG
Controlled vocabulary name: silicate
In-situ / Manipulation / Response variable: in-situ
NITRAT
Abbreviation: NITRAT
Unit: UMOL/KG
Controlled vocabulary name: NITRATE
In-situ / Manipulation / Response variable: in-situ
NITRIT
Abbreviation: NITRIT
Unit: UMOL/KG
Controlled vocabulary name: NITRITE
In-situ / Manipulation / Response variable: in-situ
PHSPHT
Abbreviation: PHSPHT
Unit: UMOL/KG
Controlled vocabulary name: phosphate
In-situ / Manipulation / Response variable: in-situ
AMMONI
Abbreviation: AMMONI
Unit: UMOL/KG
Controlled vocabulary name: AMMONIUM (NH4)
In-situ / Manipulation / Response variable: in-situ
TCARBN
Abbreviation: TCARBN
Unit: UMOL/KG
Controlled vocabulary name: DISSOLVED INORGANIC CARBON (DIC)
In-situ / Manipulation / Response variable: in-situ
ALKALI
Abbreviation: ALKALI
Unit: UMOL/KG
Controlled vocabulary name: total alkalinity
In-situ / Manipulation / Response variable: in-situ

PUBLICATIONS DESCRIBING THIS DATASET:
Mintrop, L., F.F. Pérez, M. González-Dávila, J.M. Santana-Casiano, and A. Körtzinger. Alkalinity determination by potentiometry: intercalibration using three different methods, Scienc. Mar., 26(1), 23-37, 2000.
Johnson, K., K.D. Willis, D.B. Butler, W.K. Johnson, and C.S. Wong, Coulometric carbon dioxide analysis for marine studies: Maximizing the performance of an automated gas extraction system and coulometric detector, Mar. Chem., 44(2-4), 167-188, 1993.
Körtzinger, A., A significant CO2 sink in the tropical Atlantic Ocean associated with the Amazon River plume, Geophys. Res. Lett., 30(24), 2287, https://doi.org/10.1029/2003GL018841, 2003.
Voss, M., P. Croot, K. Lochte, M. Mills, and I. Peeken, Patterns of nitrogen fixation along 10N in the tropical Atlantic, Geophys. Res. Lett., 31(23), L23S09, https://doi.org/10.1029/2004GL020127, 2004.
Wallace, D. W. R., and H. W. Bange, Introduction to special section: Results of the Meteor 55: Tropical SOLAS Expedition, Geophys. Res. Lett., 31, L23S01, https://doi.org/10.1029/2004GL021014, 2004.
Mills, M.M., C. Ridame, M. Davey, J. LaRoche, R. Geider, Iron and phosphorus co-limit nitrogen fixation in the eastern tropical North Atlantic, Nature, 429, 292-294, https://doi.org/10.1038/nature02550, 2004
Gros V., J. Williams, M.G. Lawrence, R. von Kuhlmann, J. van Aardenne, E. Atlas, A. Chuck, D.P. Edwards, V. Stroud, M. Krol, Tracing the origin and ages of interlaced atmospheric pollution events over the tropical Atlantic Ocean with in situ measurements, satellites, trajectories, emission inventories, and global models, J. Geophys. Res., 109, D22306, https://doi.org/10.1029/2004JD004846, 2004.
Walter, S., Bange, H.W., Breitenbach, U. and Wallace, D.W.R., Nitrous oxide in the North Atlantic Ocean., Biogeosci., 3, 607-619, 2006.
Baker, A.R., Weston, K., Kelley, S. D., Voss, M., Streu, P., and Cape, J. N., Dry and wet deposition of nutrients from the tropical Atlantic atmosphere: Links to primary productivity and nitrogen fixation, Deep-Sea Res. I, 54(10), 1704-1720, 2007.
Williams, J., Gros, V., Atlas, E., Macieczyk, K., Batsaikhan, A., Schoeler, H.F., Forster, C., Quack, B., Yassaa, N., Sander, R., and Van Dingenen, R., Possible evidence for a connection between methyl iodide emissions and Saharan dust, J. Geophys. Res., 112: D07302, https://doi.org/10.1029/2005JD006702, 2007.
Baker, A. R., Inorganic iodine speciation in tropical Atlantic aerosol, Geophys. Res. Lett., 31(23), L23S02, https://doi.org/10.1029/2004GL020144, 2004.
Croot, P. L., P. Streu, and A. R. Baker, Short residence time for iron in surface seawater impacted by atmospheric dry deposition from Saharan dust events, Geophys. Res. Lett., 31(23), L23S08, https://doi.org/10.1029/2004GL020153, 2004.
Croot, P. L., P. Streu, I. Peeken, K. Lochte, and A. R. Baker, Influence of the ITCZ on H2O2 in near surface waters in the equatorial Atlantic Ocean, Geophys. Res. Lett., 31(23), L23S04, https://doi.org/10.1029/2004GL020154, 2004.
Quack, B., E. Atlas, G. Petrick, V. Stroud, S. Schauffler, and D. W. R. Wallace, Oceanic bromoform sources for the tropical atmosphere, Geophys. Res. Lett., Geophys. Res. Lett., 31(23), L23S05, https://doi.org/10.1029/2004GL020597, 2004.
Richter, U. and D.W.R. Wallace, Production of methyl iodide in the tropical Atlantic Ocean, Geophys. Res. Lett., 31(23), L23S03, https://doi.org/10.1029/2004GL020779, 2004.
Walter, S., H. W. Bange, and D. W. R. Wallace, Nitrous oxide in the surface layer of the tropical North Atlantic Ocean along a west to east transect, Geophys. Res. Lett., 31(23), L23S07, https://doi.org/10.1029/2004GL019937, 2004.
Williams, J., R. Holzinger, V. Gros, X. Xu, E. Atlas, and D. W. R. Wallace, Measurements of organic species in air and seawater from the tropical Atlantic, Geophys. Res. Lett., 31(23), L23S06, https://doi.org/10.1029/2004GL020012, 2004.
ADDITIONAL INFORMATION:
none;
FUNDING AGENCY:

SUBMITTED BY: Alex Kozyr (Alex.Kozyr@noaa.gov)

SUBMISSION DATE: 2013-10-23